TOPICS
Search

Mass-Action System


A mass-action system is a polynomial ordinary differential equation associated with a reaction network, in which the flux of each reaction is proportional to the monomial of its source complex (Boros and Hofbauer 2020). For positive rate constants k_(y->y^'), its equation is

 x^.=sum_(y->y^')k_(y->y^')x^y(y^'-y),

where x^.=dx/dt is the time derivative of the concentration vector x(t), x^y=product_(i=1)^(d)x_i^(y_i) and x_i>0 is the ith concentration. The stoichiometric subspace S contains this vector field, and the positive compatibility class of x^0 is P=(x^0+S) intersection R_(>0)^d. For A⇄B with forward rate a and reverse rate b, the equations are x^._1=-ax_1+bx_2 and x^._2=ax_1-bx_2. The Schnakenberg system has a cubic monomial from a reaction with two molecules of one species and one molecule of the other in its source complex.

A global positive trajectory is persistent when

 liminf_(t->infty)x_i(t)>0,

for every species i. The system is permanent on P when one compact set K_P subset P eventually contains every positive trajectory in the class. The entry time may depend on the initial state.


See also

Dynamical System, Ordinary Differential Equation, Reaction Network, Stoichiometric Subspace, Weakly Reversible Reaction Network

Explore with Wolfram|Alpha

References

Boros, B. and Hofbauer, J. "Permanence of Weakly Reversible Mass-Action Systems with a Single Linkage Class." SIAM J. Appl. Dyn. Syst. 19, 352-365, 2020. https://doi.org/10.1137/19M1248431.

Cite this as:

Weisstein, Eric W. "Mass-Action System." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/Mass-ActionSystem.html

Subject classifications