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Magnetic Space Group


A magnetic space group (MSG), also called a Shubnikov group, is a subgroup M of the direct product of the three-dimensional Euclidean group E(3) with the time-reversal group {1,1^'},

 M subset E(3)×{1,1^'},

whose translation subgroup is generated by three linearly independent translations. An operation carrying a prime includes time reversal, while an unprimed operation is an ordinary spatial symmetry.

Let F be the family space group obtained by discarding the primes from the elements of M, and let D be the maximal ordinary space subgroup consisting of its unprimed elements. The magnetic space groups fall into four construct types (Shinohara et al. 2023):

1. Type I has M=F1=D1 and contains no time-reversal operations. There are 230 type-I groups.

2. Type II has M=F1⊔F1^' and F=D, so every spatial symmetry occurs both unprimed and primed. There are 230 type-II groups.

3. Type III has M=D1⊔(F\D)1^', where D is an index-two subgroup of F with the same translations. There are 674 type-III groups.

4. Type IV has the same coset form as type III, but D and F have the same point group and different translation subgroups. There are 517 type-IV groups.

Altogether there are 1651 three-dimensional magnetic space-group types, each with a unique Belov-Neronova-Smirnova (BNS) number. A BNS number consists of two positive integers separated by a period. The first identifies the nonmagnetic space group F for types I-III or the nonmagnetic space group of D for type IV, while the second sequentially distinguishes magnetic space groups associated with the same crystal family (Litvin 2014).


See also

Crystallographic Point Groups, Direct Product, Euclidean Group, Group Corepresentation, Point Groups, Space Groups, Subgroup, Symmetry, Translation

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References

Litvin, D. B. Magnetic Group Tables: 1-, 2- and 3-Dimensional Magnetic Subperiodic Groups and Magnetic Space Groups. Chester, England: International Union of Crystallography, 2014. https://doi.org/10.1107/9780955360220001.Shinohara, K.; Togo, A.; and Tanaka, I. "Algorithms for Magnetic Symmetry Operation Search and Identification of Magnetic Space Group from Magnetic Crystal Structure." Acta Cryst. A 79, 390-398, 2023. https://doi.org/10.1107/S2053273323005016.

Cite this as:

Weisstein, Eric W. "Magnetic Space Group." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/MagneticSpaceGroup.html

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