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Havriliak-Negami Relaxation


The Havriliak-Negami relaxation is the function

 H_(alpha,gamma)(s)=1/([1+(stau_0)^alpha]^gamma),
(1)

where tau_0>0 is a scale parameter and, conventionally, 0<alpha,gamma<=1 are shape parameters. It includes the Debye relaxation (alpha,gamma)=(1,1), the Cole-Cole relaxation gamma=1, and the Davidson-Cole relaxation alpha=1 as special cases (Havriliak and Negami 1966).

For 0<alpha<1, it has the normalized Stieltjes transform representation

 H_(alpha,gamma)(s)=int_0^infty(G_(alpha,gamma)(tau))/(1+stau)dtau,
(2)

where, on setting

 r=((tau_0)/tau)^alpha and theta=arg(1+re^(ipialpha)),
(3)

the probability density is

 G_(alpha,gamma)(tau)=(sin(gammatheta))/(pitau(1+2rcos(pialpha)+r^2)^(gamma/2)).
(4)

Here arg is the principal complex argument. Using a single-argument inverse tangent for theta without correcting its quadrant can give the wrong sign. The asymptotic behaviors of the probability density are

G_(alpha,gamma)(tau)∼(sin(pialphagamma))/(pitau_0^(alphagamma))tau^(alphagamma-1) as tau/tau_0->0
(5)
G_(alpha,gamma)(tau)∼(gammasin(pialpha)tau_0^alpha)/pitau^(-alpha-1) as tau/tau_0->infty.
(6)

(Ribeiro de Almeida et al. 2026).

For the Davidson-Cole case alpha=1 and 0<gamma<1, the corresponding probability density instead has compact support and is

 G_(1,gamma)(tau)={(sin(pigamma))/pi(tau^(gamma-1))/((tau_0-tau)^gamma)   for 0<tau<tau_0; 0   for tau>=tau_0.
(7)

At alpha=gamma=1, it degenerates to the delta function delta(tau-tau_0).


See also

Complex Argument, Delta Function, Stieltjes Transform

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References

Havriliak, S. and Negami, S. "A Complex Plane Analysis of alpha-Dispersions in Some Polymer Systems." J. Polymer Sci. Part C: Polymer Symposia 14, 99-117, 1966. https://doi.org/10.1002/polc.5070140111.Ribeiro de Almeida, R. R.; Lenzi, E. K.; and Evangelista, L. R. "Impedance Response of Electrolytic Cells with Non-Debye Relaxation Time Distributions at Adsorbing Electrodes." Electrochim. Acta 577, 149724, 2026. https://doi.org/10.1016/j.electacta.2026.149724.

Cite this as:

Weisstein, Eric W. "Havriliak-Negami Relaxation." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/Havriliak-NegamiRelaxation.html

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