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Winterbottom Shape


WinterbottomShape

A Winterbottom shape is a truncation of a Wulff shape by a half-space, followed by translation and dilation, that minimizes anisotropic surface energy with a flat substrate contact term at prescribed volume (Winterbottom 1967, Kreutz and Schmidt 2026). It is the geometric solution of the corresponding constrained problem in the calculus of variations.

Let gamma be a positive continuous function on the unit sphere whose positively homogeneous extension is convex, and let lambda be the difference between the crystal-substrate and substrate-vapor energies per unit area. For a region E above the substrate x_d=0, the energy is

 F_(lambda,gamma)(E)=int_(partialE intersection {x_d>0})gamma(nu_E)dA+lambdaA(partialE intersection {x_d=0}),

where nu_E is the outward unit normal vector and A denotes (d-1)-dimensional area. The integrals are interpreted measure-theoretically for sets of finite perimeter.

Writing e_d for the vertical unit vector, the partial-wetting range is -gamma(e_d)<lambda<gamma(-e_d). In this range the minimizing shape is

 E=a[(W_gamma intersection {x in R^d:x_d>=-lambda})+lambdae_d],

up to translation parallel to the substrate and sets of zero volume, where the positive scale factor a fixes the prescribed volume (Kreutz and Schmidt 2026). The translation by lambdae_d places the cut on the substrate. The figure above illustrates the cut for lambda=1/3 before this translation.

When gamma(n)=r is constant, the Wulff shape is a closed ball and the Winterbottom shape is a spherical cap in three dimensions. The contact angle theta, measured through the drop, satisfies costheta=-lambda/r. Thus lambda=0 gives a hemisphere, while negative lambda gives a flatter cap.


See also

Convex Body, Isoperimetric Problem, Spherical Cap, Wulff Shape

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References

Kreutz, L. and Schmidt, B. "A Note on the Winterbottom Shape." Proc. Roy. Soc. Edinburgh A 156, 2035-2048, 2026. https://doi.org/10.1017/prm.2024.118.Winterbottom, W. L. "Equilibrium Shape of a Small Particle in Contact with a Foreign Substrate." Acta Metall. 15, 303-310, 1967. https://doi.org/10.1016/0001-6160(67)90206-4.

Cite this as:

Weisstein, Eric W. "Winterbottom Shape." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/WinterbottomShape.html

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