A trivalent tree, also called a 3-valent tree or a 3-Cayley tree, is a tree for which each node has vertex degree
. The numbers of trivalent trees
on , 2, ... nodes are 1, 1, 1, 1, 2, 2,
4, 6, 11, 18, 37, 66, 135, 265, 552, ... (OEIS A000672).

The number of trees with nodes of valency either 1 or 3 for , 2, ... are 1, 1, 0, 1, 0, 1, 0, 1, 0, 2, 0, 2, 0, 4, ...
(OEIS A052120). These are sometimes called
boron trees, since such a tree with nodes has nodes of valency 3 (corresponding to boron atoms) and nodes of valency (corresponding to
hydrogen atoms) for ,
4, ....