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Oregonator


The Oregonator is a nonlinear dynamical system of three first-order ordinary differential equations modeling concentration oscillations in the Belousov-Zhabotinsky reaction (Field and Noyes 1974). In dimensionless variables x, y, and z, it is

epsilonx^'=qy-xy+x(1-x)
(1)
epsilon^'y^'=-qy-xy+fz
(2)
z^'=x-z,
(3)

where epsilon, epsilon^', q, and f are positive constants and the derivatives are with respect to dimensionless time (Field 2007). The vector field points inward or is tangent on each boundary face of the nonnegative octant, so initially nonnegative concentrations remain nonnegative.

At a positive equilibrium point, z=x and y=fx/(q+x). Substituting into the first equation gives

 x^2+(q+f-1)x-q(1+f)=0.
(4)

The negative constant term ensures that the two roots have opposite signs. The positive root therefore determines the unique positive equilibrium point.

Field and Noyes (1974) numerically found an attracting limit cycle for a parameter choice equivalent to f=1, q=8.375×10^(-6), epsilon approx 0.002084, and epsilon^' approx 0.0001042 in this scaling. The trajectory in phase space approaches the same cycle from several different sets of initial conditions.


See also

Brusselator Equations, Dynamical System, Limit Cycle

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References

Field, R. J. "Oregonator." Scholarpedia 2, 1386, 2007. https://doi.org/10.4249/scholarpedia.1386.Field, R. J. and Noyes, R. M. "Oscillations in Chemical Systems. IV. Limit Cycle Behavior in a Model of a Real Chemical Reaction." J. Chem. Phys. 60, 1877-1884, 1974. https://doi.org/10.1063/1.1681288.

Cite this as:

Weisstein, Eric W. "Oregonator." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/Oregonator.html

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