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Magic Angle


The magic angle is the angle

 theta_m=cos^(-1)(1/(sqrt(3)))=54.7356103... degrees,

at which 3cos^2theta-1=0. Equivalently, it is the acute angle for which the second Legendre polynomial P_2(costheta) vanishes.

Many anisotropic interactions contain the angular factor 3cos^2theta-1. They therefore vanish when their relevant axis makes the magic angle with a fixed direction. In solid-state nuclear magnetic resonance, magic-angle spinning uses this cancellation to average orientation-dependent broadening.

The decimal expansion of the magic angle in degrees begins 5, 4, 7, 3, 5, 6, 1, 0, 3, 1, 7, ... (OEIS A210974).


See also

Angle, Legendre Polynomial

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References

Andrew, E. R.; Bradbury, A.; and Eades, R. G. "Nuclear Magnetic Resonance Spectra from a Crystal Rotated at High Speed." Nature 182, 1659, 1958. https://doi.org/10.1038/1821659a0.Sloane, N. J. A. Sequence A210974 in "The On-Line Encyclopedia of Integer Sequences."

Cite this as:

Weisstein, Eric W. "Magic Angle." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/MagicAngle.html

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