A character table records the group characters of the irreducible representations
of a finite group. A finite
group
has a finite number of conjugacy
classes and a finite number of distinct irreducible
representations. The group character of a
group representation is constant on a conjugacy class. Hence, the values of the group
characters can be written as an array, known as a character table. Typically,
the rows are given by the irreducible representations
and the columns are given by the conjugacy classes.
A character table often contains enough information to identify a given abstract group and distinguish it from others. However, there exist
groups that are not isomorphic
which nevertheless have the same character table, for example
(the symmetry group of
the square) and
(the quaternion group).
For example, the symmetric group on three letters
has three conjugacy
classes, represented by the permutations
,
, and
. It also has three irreducible
representations; two are one-dimensional and the
third is two-dimensional:
1. The trivial representation
.
2. The alternating representation, given by the permutation signature of the permutation,
.
3. The standard representation on
with
 |
(1)
|
Using the vector basis
,
of
, the standard representation is described on
by the matrices
and hence the group character of the first matrix is 0 and that of the second is
. The group character of
the identity element is always the dimension
of the vector space. The matrix
trace of the alternating group representation
is just the permutation signature of the permutation.
Consequently, the character table for
is shown below.
| 1 | 2 | 3 |
 |  | (12) | (123) |
| trivial | 1 | 1 | 1 |
| alternating | 1 |  | 1 |
| standard | 2 | 0 |  |
Chemists and physicists use a special convention for representing character tables which is applied especially to the symmetry groups
of molecules. These include the 32 crystallographic point
groups compatible with a lattice, as well as
other finite and infinite symmetry groups. In the example above, the numbered
regions contain the following contents (Cotton 1990, pp. 90-92).
1. The symbol used to represent the group in question (in this case
).
2. The conjugacy classes, indicated by number and symbol, where the sum of the coefficients
gives the group order of the group.
3. Mulliken symbols, one for each irreducible
representation.
4. An array of the group characters of the irreducible representation of the group,
with one column for each conjugacy class, and
one row for each irreducible representation.
5. Combinations of the symbols
,
,
,
,
, and
, the first three of which represent the coordinates
,
, and
, and the last three of which stand for rotations
about these axes. These are related to transformation properties
and basis representations
of the group.
6. All square and binary products of coordinates according to their transformation
properties.
The character tables for several symmetry groups are reproduced below using this notation. For the cyclic groups, pairs of complex-conjugate
one-dimensional group
characters are displayed together in rows labeled
.
 | | | ... | | | |
 | 1 | 1
| ... | 1 |  |  |
 | 1 | 1
| ... |  |  | |
 | 2 |  | ... | 0 |  |  |
 | 2 |  | ... | 0 | |  |
 | 2 |  | ... | 0 | | |
|  |  |  |  | | |