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Boltzmann Distribution


The Boltzmann distribution is the discrete statistical distribution in which a state of energy E_i has probability

 p_i=(e^(-E_i/(k_BT)))/Z,

where

 Z=sum_(j)e^(-E_j/(k_BT)),

and T>0 is the absolute temperature, k_B>0 is the Boltzmann constant that converts temperature to energy, and the normalizing sum Z ensures that sum_(i)p_i=1. Consequently, the ratio of the probabilities of two states is p_i/p_j=e^(-(E_i-E_j)/(k_BT)).

At high temperature, states with different finite energies have more nearly equal probabilities. At low temperature, states of lower energy receive exponentially greater probability. If an energy value is shared by several states, the total probability of that energy level is multiplied by the number of states sharing it.


See also

Statistical Distribution

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References

Pathria, R. K. and Beale, P. D. Statistical Mechanics, 3rd ed. Amsterdam, Netherlands: Elsevier, 2011.

Cite this as:

Weisstein, Eric W. "Boltzmann Distribution." From MathWorld--A Wolfram Resource. https://mathworld.wolfram.com/BoltzmannDistribution.html

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