Spherical Harmonic
The spherical harmonics
are the angular portion of the solution to Laplace's
equation in spherical coordinates where
azimuthal symmetry is not present. Some care must be taken in identifying the notational
convention being used. In this entry,
is taken as
the polar (colatitudinal) coordinate with
,
and
as the azimuthal (longitudinal) coordinate
with
. This is the convention
normally used in physics, as described by Arfken (1985) and the Wolfram
Language (in mathematical literature,
usually denotes
the longitudinal coordinate and
the colatitudinal
coordinate). Spherical harmonics are implemented in the Wolfram
Language as SphericalHarmonicY[l,
m, theta, phi].
Spherical harmonics satisfy the spherical harmonic differential equation, which is given by the angular part of Laplace's
equation in spherical coordinates. Writing
in this equation
gives
 |
(1)
|
Multiplying by
gives
![[(sintheta)/(Theta(theta))d/(dtheta)(sintheta(dTheta)/(dtheta))+l(l+1)sin^2theta]+1/(Phi(phi))(d^2Phi(phi))/(dphi^2)=0.](/images/equations/SphericalHarmonic/NumberedEquation2.gif) |
(2)
|
Using separation of variables by equating the
-dependent portion to a constant gives
 |
(3)
|
which has solutions
 |
(4)
|
Plugging in (3) into (2) gives the equation for the
-dependent portion, whose solution
is
 |
(5)
|
where
,
, ..., 0,
...,
,
and
is an associated Legendre polynomial. The
spherical harmonics are then defined by combining
and
,
 |
(6)
|
where the normalization is chosen such that
 |
(7)
|
(Arfken 1985, p. 681). Here,
denotes the complex conjugate and
is the
Kronecker delta. Sometimes (e.g., Arfken 1985),
the Condon-Shortley phase
is prepended
to the definition of the spherical harmonics.
The spherical harmonics are sometimes separated into their real
and imaginary parts,
 |
(8)
|
 |
(9)
|
The spherical harmonics obey
where
is a Legendre
polynomial.
Integrals of the spherical harmonics are given by
 |
(13)
|
where
is a Wigner
3j-symbol (which is related to the Clebsch-Gordan
coefficients). Special cases include
(Arfken 1985, p. 700).

The above illustrations show
(top),
(bottom left), and
(bottom right).
The first few spherical harmonics are
Written in terms of Cartesian coordinates,
so
The zonal harmonics are defined to be those of the form
 |
(43)
|
The tesseral harmonics are those of
the form
 |
(44)
|
 |
(45)
|
for
. The sectorial
harmonics are of the form
 |
(46)
|
 |
(47)
|
SEE ALSO: Associated Legendre Polynomial,
Condon-Shortley Phase,
Correlation Coefficient,
Laplace
Series,
Sectorial Harmonic,
Solid
Harmonic,
Spherical Harmonic
Addition Theorem,
Spherical
Harmonic Differential Equation,
Spherical
Harmonic Closure Relations,
Surface Harmonic,
Tesseral Harmonic,
Vector
Spherical Harmonic,
Zonal Harmonic
RELATED WOLFRAM SITES: http://functions.wolfram.com/Polynomials/SphericalHarmonicY/,
http://functions.wolfram.com/HypergeometricFunctions/SphericalHarmonicYGeneral/
REFERENCES:
Abbott, P. "2. Schrödinger Equation." Lecture Notes for Computational
Physics 2. http://physics.uwa.edu.au/pub/Computational/CP2/2.Schroedinger.nb.
Arfken, G. "Spherical Harmonics" and "Integrals of the Products of Three Spherical Harmonics." §12.6 and 12.9 in Mathematical
Methods for Physicists, 3rd ed. Orlando, FL: Academic Press, pp. 680-685
and 698-700, 1985.
Byerly, W. E. "Spherical Harmonics." Ch. 6 in An Elementary Treatise on Fourier's Series, and Spherical, Cylindrical, and Ellipsoidal
Harmonics, with Applications to Problems in Mathematical Physics. New York:
Dover, pp. 195-218, 1959.
Ferrers, N. M. An Elementary Treatise on Spherical Harmonics and Subjects Connected with Them.
London: Macmillan, 1877.
Groemer, H. Geometric Applications of Fourier Series and Spherical Harmonics. New York: Cambridge
University Press, 1996.
Hobson, E. W. The
Theory of Spherical and Ellipsoidal Harmonics. New York: Chelsea, 1955.
Kalf, H. "On the Expansion of a Function in Terms of Spherical Harmonics in Arbitrary Dimensions." Bull. Belg. Math. Soc. Simon Stevin 2,
361-380, 1995.
MacRobert, T. M. and Sneddon, I. N. Spherical Harmonics: An Elementary Treatise on Harmonic Functions, with Applications, 3rd ed.
rev. Oxford, England: Pergamon Press, 1967.
Normand, J. M. A Lie Group: Rotations in Quantum Mechanics. Amsterdam, Netherlands: North-Holland,
1980.
Press, W. H.; Flannery, B. P.; Teukolsky, S. A.; and Vetterling, W. T. "Spherical Harmonics." §6.8 in Numerical
Recipes in FORTRAN: The Art of Scientific Computing, 2nd ed. Cambridge, England:
Cambridge University Press, pp. 246-248, 1992.
Sansone, G. "Harmonic Polynomials and Spherical Harmonics," "Integral Properties of Spherical Harmonics and the Addition Theorem for Legendre Polynomials,"
and "Completeness of Spherical Harmonics with Respect to Square Integrable Functions."
§3.18-3.20 in Orthogonal
Functions, rev. English ed. New York: Dover, pp. 253-272, 1991.
Sternberg, W. and Smith, T. L. The Theory of Potential and Spherical Harmonics, 2nd ed. Toronto: University
of Toronto Press, 1946.
Wang, J.; Abbott, P.; and Williams, J. "Visualizing Atomic Orbitals." http://physics.uwa.edu.au/pub/Orbitals.
Weisstein, E. W. "Books about Spherical Harmonics." http://www.ericweisstein.com/encyclopedias/books/SphericalHarmonics.html.
Whittaker, E. T. and Watson, G. N. "Solution of Laplace's Equation Involving Legendre Functions" and "The Solution of Laplace's Equation which
Satisfies Assigned Boundary Conditions at the Surface of a Sphere." §18.31
and 18.4 in A
Course in Modern Analysis, 4th ed. Cambridge, England: Cambridge University
Press, pp. 391-395, 1990.
Zwillinger, D. Handbook of Differential Equations, 3rd ed. Boston, MA: Academic Press, p. 129,
1997.
Referenced on Wolfram|Alpha:
Spherical Harmonic
CITE THIS AS:
Weisstein, Eric W. "Spherical Harmonic."
From MathWorld--A Wolfram Web Resource. http://mathworld.wolfram.com/SphericalHarmonic.html